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Vial: difference between revisions

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Revision 19 — 05:18, 16 Oct 2024
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1{{Infobox concept1{{Infobox concept
2| name = Vial2| name = Vial
+3| image = vial.svg
+4| caption = A tubing-drawn vial with an elastomeric closure and crimped aluminium ferrule. The three components together constitute the container closure system.
3| Function = Primary container for injectable and lyophilised products5| Function = Primary container for injectable and lyophilised products
4| Usual material = Type I borosilicate glass6| Usual material = Type I borosilicate glass
60Dimensions are nominal and subject to the tolerances in the standard.{{r|iso8362_1}} Two consequences follow for reading a label. A vial described as a 2 mL vial holds about 4 mL brimful, so a 2R vial containing 1 mL of liquid looks nearly empty and a 2R vial containing a 5 mg lyophilised cake may appear to contain nothing at all. And the neck finish, not the nominal capacity, determines which closure fits — 13 mm and 20 mm are not interchangeable, and a 20 mm stopper on a 13 mm vial cannot be sealed.62Dimensions are nominal and subject to the tolerances in the standard.{{r|iso8362_1}} Two consequences follow for reading a label. A vial described as a 2 mL vial holds about 4 mL brimful, so a 2R vial containing 1 mL of liquid looks nearly empty and a 2R vial containing a 5 mg lyophilised cake may appear to contain nothing at all. And the neck finish, not the nominal capacity, determines which closure fits — 13 mm and 20 mm are not interchangeable, and a 20 mm stopper on a 13 mm vial cannot be sealed.
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+64== Elastomeric closures ==
+65The stopper performs three functions: it seals, it is penetrable by a needle and reseals afterwards, and it must not contribute leachables to the product. No single elastomer optimises all three, and formulation is a compromise.
+66
+67|+ Closure elastomers in pharmaceutical use
+68| !Elastomer | Gas and moisture permeability | Resealing | Typical role |
+69|---|---|---|---|
+70| Bromobutyl rubber | Low | Good | Standard for lyophilised and aqueous parenterals |
+71| Chlorobutyl rubber | Low | Good | Standard alternative; different cure chemistry |
+72| Natural rubber | High | Very good | Largely superseded; latex protein concerns |
+73| Silicone | Very high | Good | Specialised, where extractables must be minimal |
+74| Isoprene blends | Intermediate | Good | Occasional, in blends |
+75
+76Butyl elastomers dominate because their low permeability protects a lyophilised cake from moisture ingress and an oxygen-sensitive product from oxidation over a multi-year shelf life. A closure formulation is a mixture of elastomer, filler, curing system, pigment and lubricant, and the components other than the elastomer are frequently the source of the extractables that make a closure unsuitable for a particular product.{{r|usp381,usp1381}}
+77
62== References ==78== References ==
63{{reflist}}79{{reflist}}
65<ref name="usp661">United States Pharmacopeia, General Chapter <661>, "Plastic Packaging Systems and Their Materials of Construction". USP–NF, current revision.</ref>81<ref name="usp661">United States Pharmacopeia, General Chapter <661>, "Plastic Packaging Systems and Their Materials of Construction". USP–NF, current revision.</ref>
66<ref name="usp381">United States Pharmacopeia, General Chapter <381>, "Elastomeric Closures for Injections". USP–NF, current revision.</ref>82<ref name="usp381">United States Pharmacopeia, General Chapter <381>, "Elastomeric Closures for Injections". USP–NF, current revision.</ref>
+83<ref name="usp1381">United States Pharmacopeia, General Chapter <1381>, "Assessment of Elastomeric Components Used in Injectable Pharmaceutical Product Packaging/Delivery Systems" (informational). USP–NF, current revision.</ref>
67<ref name="usp1207">United States Pharmacopeia, General Chapter <1207>, "Package Integrity Evaluation — Sterile Products" (informational), with subchapters <1207.1> to <1207.3>. USP–NF, current revision.</ref>84<ref name="usp1207">United States Pharmacopeia, General Chapter <1207>, "Package Integrity Evaluation — Sterile Products" (informational), with subchapters <1207.1> to <1207.3>. USP–NF, current revision.</ref>
68<ref name="iso8362_1">ISO 8362-1:2018, ''Injection containers and accessories — Part 1: Injection vials made of glass tubing'', read with ISO 8362-4:2011, ''Part 4: Injection vials made of moulded glass''. International Organization for Standardization.</ref>85<ref name="iso8362_1">ISO 8362-1:2018, ''Injection containers and accessories — Part 1: Injection vials made of glass tubing'', read with ISO 8362-4:2011, ''Part 4: Injection vials made of moulded glass''. International Organization for Standardization.</ref>
77[[Category:Manufacturing and supply]]94[[Category:Manufacturing and supply]]
78[[Category:Compendial testing]]95[[Category:Compendial testing]]
+96[[Category:Traceability]]
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