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Residual solvent: difference between revisions

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Revision 1 — 09:00, 2 Sep 2024
AAA_Analyst (talk)
new article: analytical method, expansion welcome
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Revision 2 — 08:57, 8 Sep 2024
NewLabNell (talk)
ce per PP:MOS
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10In peptide manufacture the solvents of interest are those used in [[Solid-phase peptide synthesis|synthesis]], cleavage and purification — dimethylformamide, dichloromethane, acetonitrile, methanol, trifluoroacetic acid and diethyl ether among them. Several fall in Class 2 and are limited accordingly.{{r|usp467}}10In peptide manufacture the solvents of interest are those used in [[Solid-phase peptide synthesis|synthesis]], cleavage and purification — dimethylformamide, dichloromethane, acetonitrile, methanol, trifluoroacetic acid and diethyl ether among them. Several fall in Class 2 and are limited accordingly.{{r|usp467}}
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+12== Classes and limits ==
+13| Class | Basis | Examples relevant to peptides | Control |
+14|---|---|---|---|
+15| 1 | Known or suspected human carcinogen | Benzene, carbon tetrachloride | To be avoided |
+16| 2 | Non-genotoxic animal carcinogen or other toxicity | Dichloromethane, methanol, acetonitrile, N,N-dimethylformamide | Limited by specified concentration |
+17| 3 | Low toxic potential | Acetic acid, ethanol, diethyl ether, acetone | Generally limited at 0.5% |
+18
+19Limits for Class 2 solvents are derived from a permitted daily exposure and a maximum daily dose, so a concentration limit depends on how much substance is administered. A concentration expressed without reference to that basis cannot be assessed against a limit.{{r|ich_q3c}}
+20
12== References ==21== References ==
13{{reflist}}22{{reflist}}